NONSTEREOSPECIFICITY IN THE CYCLOADDITIONS OF KETENEIMINIUM SALTS TO OLEFINS. EVIDENCE FOR A STEPWISE MECHANISM.

DOI: 10.1016/S0040-4039(00)81896-1

Source and publish data:

Tetrahedron Letters p. 2251 - 2254 (1983)

Update date:2022-08-05

Topics:

Authors:

Saimoto, Hiroyuki

Houge, Catherine

Hesbain-Frisque, Anne-Marie

Mockel, Anne

Ghosez, Leon

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Article abstract of DOI:10.1016/S0040-4039(00)81896-1

The stereospecificity of the olefin-keteneiminium salt reaction is shown to be dependent on the nitrogen substituents.This is taken as evidence for a stepwise mechanism.

Full text of DOI:10.1016/S0040-4039(00)81896-1

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