Intramolecular Diels-Alder reactions of silyl acetal trienes. The effect on stereoselectivity of allylic substitution

DOI: 10.1016/0040-4039(92)88103-C

Source and publish data:

Tetrahedron Letters p. 4073 - 4076 (1992)

Update date:2022-08-05

Topics:

Authors:

Craig Craig

Reader Reader

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(92)88103-C

The syntheses and thermal intramolecular Diels-Alder reactions of silyl acetal trienes possessing methyl groups at the allylic positions of the diene or dienophile are described. A model is proposed to account for the observed selectivities. The structure

Full text of DOI:10.1016/0040-4039(92)88103-C

Products guided by the article

Product name:Propanoic acid, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (2S)-

Cas No:87681-25-2

R&D Labs maybe for 87681-25-2

Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
Beijing Mashi Fine Chemical Co.,Ltd.

Contact:+86-10-61271592

Address:Room 506, Section B, Kaichi Mansion, Industrial Development
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
ChangZhou Mascotchem. Co.,Ltd.

website:http://www.mascotchem.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China

Relevant to this article

Doi:10.1021/ja01875a006
(1939)
Unusual reactions of {μ-(phthalazine-N²:N³)} Fe₂(μ-CO)(CO)₆ with organolithium reagents. A novel coordination mode of 1,2-diazane diiron carbonyl compounds

Doi:10.1039/b510676c
(2006)
Stereocontrolled approaches to 9 (O)-methanoprostacyclin

Doi:10.1016/S0040-4039(01)86362-0
(1979)
Catalyst free sequential one-pot reaction for the synthesis of 3-indole propanoates/propanoic acid/propanamides as antituberculosis agents

Doi:10.1002/jccs.202000386
(2021)
Antitumor activity of isochromanyltropolones

Doi:10.1248/cpb.31.2952
(1983)
Development of a Multikilogram Scale Synthesis of a TRPV1 Antagonist

Doi:10.1021/acs.oprd.5b00388
(2016)

Article Doi