1,2,4-TRIAZOLIUM-YLURES-VIII; REACTIONS DES TRIAZOLIUM-PHENACYLURES AVEC LES HETEROCUMULENES

DOI: 10.1016/S0040-4020(01)91968-4

Source and publish data:

Tetrahedron p. 2417 - 2420 (1983)

Update date:2022-08-05

Topics:

Authors:

Petrovanu, M.

Luchian, C.

Surpateanu, G.

Barboiu, V.

Constantinescu, M.

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Article abstract of DOI:10.1016/S0040-4020(01)91968-4

The reaction of 4-aryl-1,2,4-triazolium-phenacylides with heterocumulenes is discussed using orbital theory.The theoretical data are verified by experiment.The ylide carbanion acts as a nucleophilic reagent on heterocumulene giving disubstitued carbanion triazolium-ylides 3-6.

Full text of DOI:10.1016/S0040-4020(01)91968-4

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