A New Reaction of α-Nitro Nitriles: Conversion to β-Nitro Nitriles

DOI: 10.1021/jo00176a027

Source and publish data:

Journal of Organic Chemistry p. 358 - 362 (1984)

Update date:2022-08-03

Topics:

Authors:

Kornblum, Nathan

Singh, Haribansh K.

Boyd, Steven D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00176a027

At room temperature the nitro group of an α-nitro nitrile is readily displaced by nitroparaffin anions with the result that β-nitro nitriles are produced in excellent yields.Evidence is presented for the view that these reactions are electron-transfer cha

Full text of DOI:10.1021/jo00176a027

Products guided by the article

Product name:Cyclohexanecarbonitrile, 1-(1-nitroethyl)-

Cas No:87740-89-4

R&D Labs maybe for 87740-89-4

shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Hangzhou LINGEBA Technology Co., Ltd.

Contact:+0086-571-87389059

Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
Quzhou Aokai Chemical Co., Ltd.

Contact:86-570-3032832

Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China

Relevant to this article

Synthesis, mesomorphic and dielectric properties of 4-(cyanomethoxy)phenyl 4-alkoxybenzoates, 4-(cyanomethoxy)-4′-alkoxyazo- and -azoxybenzenes

Doi:10.1134/S1070428014050017
(2014)
1-Acylmethylbenzimidazole-2-sulfonic acids and their cyclization by N-nucleophiles

Doi:10.1134/S1070428014050169
(2014)
Palladium catalyzed, heteroatom-guided C-H functionalization in the synthesis of substituted isoquinolines and dihydroisoquinolines

Doi:10.1039/c4cc03165b
(2014)
Access to pyridyl-substituted 1,3,5-triazines from 4 H-pyrido[1,3]oxazin-4- ones via a cyclocondensation process

Doi:10.1021/jo5010668
(2014)
A highly efficient oxidative condensation reaction for selective protein conjugation

Doi:10.1039/c4cc01551g
(2014)
Arm-cleavable microgel star polymers: A versatile strategy for direct core analysis and functionalization

Doi:10.1021/ja505646p
(2014)

Article Doi