Synthesis of α,β-Unsaturated Carbonyl Compounds by Successive Rearrangement and Peterson Olefination of β'-Hydroxy-α,β-epoxysilanes

DOI: 10.1039/c39830001024

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Journal of the Chemical Society. Chemical communications p. 1024 - 1025 (1983)

Update date:2022-08-05

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Authors:

Sato, Fumie

Tanaka, Youichi

Kanbara, Hiroshi

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Article abstract of DOI:10.1039/c39830001024

The reaction of β'-hydroxy-α,β-epoxysilanes with boron trifluoride-diethyl ether results in rearrangement of the epoxysilane skeleton followed by Peterson olefination, leading to α,β-unsaturated carbonyl compounds.

Full text of DOI:10.1039/c39830001024

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