SIMPLE TOTAL SYNTHESES OF (+/-)-ACORAGERMACRONE AND (+/-)-MUKULOL BY INTRAMOLECULAR ALKYLATION OF PROTECTED CYANOHYDRIN

DOI: 10.1016/S0040-4039(00)86019-0

Source and publish data:

Tetrahedron Letters p. 3485 - 3488 (1983)

Update date:2022-07-29

Topics:

Authors:

Takahashi, Takashi

Nemoto, Hisao

Tsuji, Jiro

Miura, Iwao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)86019-0

Total syntheses of (+/-)-Acoragermacrone (5) and (+/-)-Mukulol (10) by the intramolecular alkylation of a carbanion generated from protected cyanohydrin with secondary tosylate are presented.

Full text of DOI:10.1016/S0040-4039(00)86019-0

Products guided by the article

Product name:Toluene-4-sulfonic acid (4E,8E,12E)-14-(1-ethoxy-ethoxy)-1-isopropyl-4,8,12-trimethyl-tetradeca-4,8,12-trienyl ester

Cas No:87920-59-0

R&D Labs maybe for 87920-59-0

Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue
shanghai meicheng chemical co .,ltd(expird)

Contact:+86-21-50677091

Address:Room 302, Building 7, No.1000, Jinhai Road
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA

Relevant to this article

N-Heterocyclic germylenes: Structural characterisation of some heavy analogues of the ubiquitous N-heterocyclic carbenes

Doi:10.1155/2019/9178371
(2019)
SYNTHESES AND PROPERTIES OF 2,5-ETHENO<4.2.2>PROPELLA-3,7,9-TRIENE AND ITS DERIVATIVES

Doi:10.1016/S0040-4039(00)86270-X
(1983)
Synthesis of 26,27-bisnorcastasterone analogs and analysis of conformation-activity relationship for brassinolide-like activity

Doi:10.1016/j.bmc.2005.10.024
(2006)
Fused polycyclic nitrogen-containing heterocycles 24.* Three-component condensation of diethyl 2, 4, 6-trioxoheptanedicarboxylate with salicylaldehydes and ammonium acetate as a new method for the synthesis of 7-and 9-substituted benzo[e]pyrano[4, 3-b]pyr

Doi:10.1007/s11172-009-0195-z
(2009)
Transformations of benzothiadiphosphole system: General one-pot synthesis of 1,2,5-dithiaphosphepines and their precursor phosphanethiols

Doi:10.1002/hc.20099
(2005)
Synthesis, Characterization and Catalytic Activity of a Tungsten(VI) Amino Triphenolate Complex

Doi:10.1007/s10562-017-2144-z
(2017)

Article Doi