Photolysis of Re2(CO)10 in the Presence of Simple Olefins. Thermal Reactivity of (μ-Hydrido)(μ-alkenyl)dirhenium Octacarbonyl Compounds

DOI: 10.1021/ja00315a032

Source and publish data:

Journal of the American Chemical Society p. 644 - 652 (1984)

Update date:2022-08-03

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Authors:

Nubel, Philip O.

Brown, Theodore L.

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Article abstract of DOI:10.1021/ja00315a032

Photolysis of Re2(CO)10 at 25 ^oC in the presence of ethylene, terminal olefins, or 2-butene results in formation of (μ-hydrido)(μ-alkenyl)dirhenium octacarbonyl complexes in high yield.The bridging alkenyl ligand forms a ? bond to one Re and a

Full text of DOI:10.1021/ja00315a032

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