Journal of Organometallic Chemistry p. C21 - C24 (1982)
Update date:2022-09-26
Topics:
Jaouen, Gerard
Johnson, Brian F. G.
Lewis, Jack
2,4-Cyclohexadien-1-yldimethylphenylphosphonium tetrafluoroborate obtained from the reaction of 2,4-cyclohexadien-1-yltricarbonyliron with PMe2Ph in 96percent yield, reacts readily with benzaldehyde in the presence of base to give 1-benzylidene-2,4-cyclohexadienetricarbonyliron in 90percent yield; this and other related reactions provide the first examples of the Wittig reaction adjacent to a tricarbonyl moiety.
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