Tetrahedron Letters p. 4021 - 4024 (1983)
Update date:2022-07-29
Topics:
Nishiyama, Hisao
Sakuta, Koji
Osaka, Noriyuki
Itoh, Kenji
Cyclic (E)-β-trimethylsilylketoxime acetates were effectively cleaved by a catalytic action of trimethylsilyl trifluoromethanesulfonate to give the corresponding unsaturated nitriles.The fragmentation in the Beckmann rearrangement is completely controlled
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(1984)