SYNTHESIS AND REACTIVITY TOWARD REDUCING AGENTS OF THE ETHOXYCARBONYL COMPLEX BPh4 (np3 = tris(2-diphenylphosphinoethyl)amine)

DOI: 10.1016/0022-328X(84)80663-4

Source and publish data:

Journal of Organometallic Chemistry p. 413 - 420 (1984)

Update date:2022-07-29

Topics:

Authors:

Bianchini, Claudio

Meli, Andrea

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Article abstract of DOI:10.1016/0022-328X(84)80663-4

The ethoxycarbonyl complex <(np3)Ni(CO2Et)BPh4 (2) has been synthesized by ethoxide ion attack on (np3)Ni(CO) (3) or <(np3)Ni(CO)>BPh4 (4).Compound 2 reacts with LiHBEt3, NaBH4, MeMgI, NaC10H8, or MeLi to give t

Full text of DOI:10.1016/0022-328X(84)80663-4

Products guided by the article

Product name:[(((C₆H₅)2PCH₂CH₂)3NH)Ni(CO)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3NH)Ni(CO)]B(C₆H₅)4

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