Tetrahedron p. 2863 - 2868 (1983)
Update date:2022-08-04
Barluenga, Jose
Lopez-Prado, Joaquin
Campos, Pedro J.
Asensio, Gregorio
β-Alkoxy- and β-hydroxyalkyl radicals generated by sodium borohydride reduction of oxymercurials react with electron deficient olefins to give addition compounds in a homogeneous process.Heterogeneous reactions are also successful in the presence of catalytic amounts of surfactants and provide a superior method for the "one pot" reductive alkylation of oxymercurials.
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