Journal of Organic Chemistry p. 3325 - 3327 (2006)
Update date:2022-07-29
Topics: Synthesis Palladium-Catalyzed Organic halides Carboannulation Indenes
Guo, Li-Na
Duan, Xin-Hua
Bi, Hai-Peng
Liu, Xue-Yuan
Liang, Yong-Min
Highly substituted indenes have been prepared in good yields by the palladium-catalyzed carboannulation of diethyl 2-(2-(1-alkynyl)phenyl)malonate with aryl, benzylic, and alkenyl halides. The reaction conditions and the scope of the process were examined, and a possible mechanism is proposed.
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