Helvetica Chimica Acta p. 2236 - 2251 (1983)
Update date:2022-07-29
Topics:
Weck, Guy de
Nakamura, Norio
Tsutsumi, Kentaro
Wolf, Hans Richard
Frei, Bruno
Jeger, Oskar
On singlet excitation (λ=254 nm) in MeCN the hydroxy-epoxydiene (E)-4 undergoes photocleavage to the carbene intermediates d and e as main processes.The carbene d, showing behaviour typical of vinyl carbenes, undergoes addition to the adjacent double bond
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