Tetrahedron Asymmetry p. 1120 - 1124 (2006)
Update date:2022-07-29
Topics:
Cuny, Eckehard
Lichtenthaler, Frieder W.
A simple and concise synthesis of the antibiotic spectinomycin is described. The key step comprises a reaction cascade initiated by the β-selective 5-O-glycosylation of an N,N-blocked myo-1,3-inosadiamine 10 with a suitable actinospectosyl donor-the d-glu
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