Diels-Alder reaction of 1-phenylsulfonyl-3,3,3-trifluoropropyne with 1,3-dienes

DOI: 10.1016/0022-1139(93)02944-A

Source and publish data:

Journal of Fluorine Chemistry p. 215 - 218 (1994)

Update date:2022-07-30

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Authors:

Hu, Chang-Ming

Hong, Feng

Jiang, Biao

Xu, Yuanyao

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Article abstract of DOI:10.1016/0022-1139(93)02944-A

1-Phenylsulfonyl-3,3,3-trifluoropropyne, prepared in situ from 1-phenylsulfonyl-2-bromo-3,3,3-trifluoropropene and triethylamine, reacted with 1,3-dienes to give the <4+2> cycloadducts and/or 2-trifluoromethyl phenylsulfone in good to excellent yield.

Full text of DOI:10.1016/0022-1139(93)02944-A

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