Nickel-catalysed Butatriene Cyclizations: a Simple and Efficient Synthesis of Radialenes (Polymethylenecycloalkanes)

DOI: 10.1039/c39830001058

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1058 - 1059 (1983)

Update date:2022-07-29

Topics:

Authors:

Iyoda, Masahiko

Tanaka, Shigeyoshi

Nose, Masanori

Oda, Masaji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001058

Treatment of 3,4-dihalogeno-2,5-dimethylhexa-2,4-dienes (1) and (5) with tetrakis(triphenylphosphine)nickel(0) in benzene, tetrahydrofuran, or N,N-dimethylformamide at 50 deg C yields octamethyl<4>radialene (2) and/or dodecamethyl<6>radialene (3), in fair

Full text of DOI:10.1039/c39830001058

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:Cyclohexane, (1-methylethenyl)pentakis(1-methylethylidene)-

Cas No:88919-68-0

R&D Labs maybe for 88919-68-0

SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province

Relevant to this article

Formal total synthesis of the cytotoxic marine ascidian alkaloid haouamine A

Doi:10.1021/ol060556c
(2006)
Chiral Thioureas Promote Enantioselective Pictet-Spengler Cyclization by Stabilizing Every Intermediate and Transition State in the Carboxylic Acid-Catalyzed Reaction

Doi:10.1021/jacs.7b06811
(2017)
Electroselective and Controlled Reduction of Cyclic Imides to Hydroxylactams and Lactams

Doi:10.1021/acs.orglett.1c00430
(2021)
Total enantioselective synthesis of the marine sesquiterpene nanaimoal

Doi:10.1039/c39940002781
(1994)
A Stereoselective Synthesis of (+/-)-Actinobolamine

Doi:10.1039/c39900001412
(1990)
Synthesis of 1,2,3,5-Tetra-O-acetyl-4-deoxy-4-C-<(RS)-ethylphosphinyl>-α,β-D-ribo- and -L-lyxofuranoses and Their Structural Analysis by 400-MHz Proton Nuclear Magnetic Resonance

Doi:10.1021/jo00182a010
(1984)

Article Doi