A Stereoselective Synthesis of (+/-)-Actinobolamine

DOI: 10.1039/c39900001412

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1412 - 1414 (1990)

Update date:2022-07-29

Topics:

Authors:

Holmes, Andrew B.

Kee, Alexander

Ladduwahetty, Tamara

Smith, David F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001412

A three-step sequence involving an imino ester heterocycloaddition, stereoselective epoxidation of the adduct 4 and subsequent toluene-p-sulphonic acid-promoted rearrangement afforded the 6-azabicyclo<3.2.1>octane 7 in excellent overall yield; elaboration

Full text of DOI:10.1039/c39900001412

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(1S,3S,4R)-2-(Toluene-4-sulfonyl)-2-aza-bicyclo[2.2.2]oct-5-ene-3-carboxylic acid methyl ester

Cas No:89357-85-7

R&D Labs maybe for 89357-85-7

Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
lianyungang jinkang pharmaceutical technology co., ltd.

Contact:008651885445517

Address:Jinshan industrial park, Ganyu county, Lianyungang, Jiangsu Province, 222115, China
HUNAN OUYA BIOLOGICAL CO.,LTD

Contact:+8613400661290

Address:No 908,Kangwan Rd, Liuyang Economic
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China
Weifang Adde Economic And Trade Co.,LTD.

Contact:86-536-8885548

Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District

Relevant to this article

Rhodium-catalyzed intramolecular conjugate addition of vinylstannanes to?dihydro-4-pyridones: a simple method for stereoselective construction of 1-azabicyclic alkaloids

Doi:10.1016/j.tet.2008.02.021
(2008)
Spirofused and Annulated 1,2,4-Trioxepane-, 1,2,4-Trioxocane-, and 1,2,4-Trioxonane-Cyclohexadienones: Cyclic Peroxides with Unusual Ring Conformation Dynamics

Doi:10.1002/anie.201807485
(2018)
The synthesis and biological evaluation of two analogues of the C-riboside showdomycin

Doi:10.1071/CH04273
(2005)
An easy route to exotic 9-epimers of 9-amino-(9-deoxy) cinchona alkaloids with (8S, 9R) and (8R, 9S)-configurations through two inversions of configuration

Doi:10.1016/j.cclet.2013.12.008
(2014)
TOTAL SYNTHESIS OF (+/-)-AVENACIOLIDE VIA THE β-VINYLBUTENOLIDE ANNULATION

Doi:10.1246/cl.1983.881
(1983)
Axial-Ligand Control of the Photophysical Behavior of Ruthenium(II) Tetraphenyl- and Octaethylporphyrin. Contrasting Properties of Metalloporphyrin (?,?^*) and (d,?^*) Excited States

Doi:10.1021/j100314a026
(1988)

Article Doi