A Stereoselective Synthesis of (+/-)-Actinobolamine

DOI: 10.1039/c39900001412

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1412 - 1414 (1990)

Update date:2022-07-29

Topics:

Authors:

Holmes, Andrew B.

Kee, Alexander

Ladduwahetty, Tamara

Smith, David F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001412

A three-step sequence involving an imino ester heterocycloaddition, stereoselective epoxidation of the adduct 4 and subsequent toluene-p-sulphonic acid-promoted rearrangement afforded the 6-azabicyclo<3.2.1>octane 7 in excellent overall yield; elaboration

Full text of DOI:10.1039/c39900001412

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(1S,3S,4R)-2-(Toluene-4-sulfonyl)-2-aza-bicyclo[2.2.2]oct-5-ene-3-carboxylic acid methyl ester

Cas No:89357-85-7

R&D Labs maybe for 89357-85-7

Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )

Relevant to this article

Rhodium-catalyzed intramolecular conjugate addition of vinylstannanes to?dihydro-4-pyridones: a simple method for stereoselective construction of 1-azabicyclic alkaloids

Doi:10.1016/j.tet.2008.02.021
(2008)
Spirofused and Annulated 1,2,4-Trioxepane-, 1,2,4-Trioxocane-, and 1,2,4-Trioxonane-Cyclohexadienones: Cyclic Peroxides with Unusual Ring Conformation Dynamics

Doi:10.1002/anie.201807485
(2018)
The synthesis and biological evaluation of two analogues of the C-riboside showdomycin

Doi:10.1071/CH04273
(2005)
An easy route to exotic 9-epimers of 9-amino-(9-deoxy) cinchona alkaloids with (8S, 9R) and (8R, 9S)-configurations through two inversions of configuration

Doi:10.1016/j.cclet.2013.12.008
(2014)
TOTAL SYNTHESIS OF (+/-)-AVENACIOLIDE VIA THE β-VINYLBUTENOLIDE ANNULATION

Doi:10.1246/cl.1983.881
(1983)
Axial-Ligand Control of the Photophysical Behavior of Ruthenium(II) Tetraphenyl- and Octaethylporphyrin. Contrasting Properties of Metalloporphyrin (?,?^*) and (d,?^*) Excited States

Doi:10.1021/j100314a026
(1988)

Article Doi