Chemistry Letters p. 1593 - 1596 (1983)
Update date:2022-07-31
Topics: Cleavage Facile Experimental Hydride
Takano, Seiichi
Akiyama, Masashi
Sato, Seiji
Ogasawara, Kunio
Benzylidene acetals of 1,2- and 1,3-glycols are easily cleft by diisobutylaluminum hydride in a toluene solution at 0 deg C - room temperature to give the corresponding monobenzyl ethers of the glycols.In general the reaction proceeds excellently in regioselective manner depending on the stereochemical environment.
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