COMPLEX FORMATION BETWEEN NICKEL(0) AND A PHOSPHAALKENE: INFLUENCE OF THE SECOND LIGAND ON THE η1- AND η2-COORDINATION MODE

DOI: 10.1016/0022-328X(83)80143-0

Source and publish data:

Journal of Organometallic Chemistry p. C33 - C36 (1983)

Update date:2022-08-03

Topics:

Authors:

Knaap, Theodorus A. van der

Jenneskens, Leo W.

Meeuwissen, Hendrik J.

Bickelhaupt, Friedrich

Walther, Dirk

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(83)80143-0

The η²-complex (bipy)Ni(XyP=CPh2) has been prepared and its structure determined by X-ray analysis.In contrast, Ni(CO)4 forms η¹-complexes by replacement of one or two CO ligands by XyP=CPh2.

Full text of DOI:10.1016/0022-328X(83)80143-0

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