Studies Related to Thromboxane A2: A Formal Synthesis of Optically Active 9α,11α-Thiathromboxane A2 Methyl Ester from Levoglucosan

DOI: 10.1021/jo00183a016

Source and publish data:

Journal of Organic Chemistry p. 1554 - 1563 (1984)

Update date:2022-08-04

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Authors:

Kale, Vilas N.

Clive, Derrick L. J.

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Article abstract of DOI:10.1021/jo00183a016

A synthesis of (+/-)-7-exo-(n-butyloxy)-2-oxa-6-thiabicyclo<3.1.1>heptane (4) from 2-(benzyloxy)-5,6-dihydropyran (5) (Scheme I) and the conversion of levoglucosan 20 into 36 (Scheme IV) are described.Compound 36 is an intermediate in a published synthesis (Scheme III) of the biologically active 9α,11α-thiathromboxane A₂ methyl ester (19).

Full text of DOI:10.1021/jo00183a016

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