AN UMPOLUNG OF ARYL AND VINYL HALIDES USING TRIS-(TRIMETHYLSILYL)ALUMINUM AND APROACH TO META- AND PARA-BRIDGED AROMATICS

DOI: 10.1016/S0040-4039(01)99804-1

Source and publish data:

Tetrahedron Letters p. 4895 - 4898 (1983)

Update date:2022-08-04

Topics:

Authors:

Trost, Barry M.

Yoshida, Jun-ichi

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Article abstract of DOI:10.1016/S0040-4039(01)99804-1

Nickel and palladium catalysts effect the chemoselective and stereocontrolled umpolung of aryl and vinyl halides to trimethylsilyl derivatives; this reaction permits a regioselective approach to cyclophanes.

Full text of DOI:10.1016/S0040-4039(01)99804-1

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