Journal of the Chemical Society. Chemical communications p. 985 - 987 (1983)
Update date:2022-08-03
Topics:
Wicha, Jerzy
Kabat, Marek M.
A synthesis of digitoxigenin (1) from 3β-acetoxyandrost-5-en-17-one (2) has been developed in which the key step involved a rearrangement of the allylic epoxide (8) to the butanolide (9) induced by tetrakis(triphenylphosphine)palladium(0).
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(1969)
