The Phosphinomethylsilyl Group as a Bifunctional Bridging Ligand. X-Ray Crystal Structure of Hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl)diruthenium(II), and of its Reaction Product with Trifluoroacetic Acid, a Mononuclear Ruthenium(II) Complex incorporating a Unique Co-or...

DOI: 10.1039/c39830001523

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Journal of the Chemical Society. Chemical communications p. 1523 - 1525 (1983)

Update date:2022-07-29

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Authors:

Auburn, Mary J.

Holmes-Smith, Rupert D.

Stobart, Stephen R.

Zaworotko, Michael J.

Cameron, T. Stanley

Kumari, Amrita

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Article abstract of DOI:10.1039/c39830001523

Reaction between Ru3(CO)12 and Ph2PCH2SiMe2H affords the symmetrical bridged diruthenium complex Me2)2(CO)6> in which Ru-Ru = 3.056(1) Angstroem; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex H)(CO)2(CO2CF3)2*Et2O> in which Ru-OSi = 2.19 Angstroem, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ...O 2.64 Angstroem.

Full text of DOI:10.1039/c39830001523

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