The Phosphinomethylsilyl Group as a Bifunctional Bridging Ligand. X-Ray Crystal Structure of Hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl)diruthenium(II), and of its Reaction Product with Trifluoroacetic Acid, a Mononuclear Ruthenium(II) Complex incorporating a Unique Co-or...

DOI: 10.1039/c39830001523

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1523 - 1525 (1983)

Update date:2022-07-29

Topics:

Authors:

Auburn, Mary J.

Holmes-Smith, Rupert D.

Stobart, Stephen R.

Zaworotko, Michael J.

Cameron, T. Stanley

Kumari, Amrita

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001523

Reaction between Ru3(CO)12 and Ph2PCH2SiMe2H affords the symmetrical bridged diruthenium complex Me2)2(CO)6> in which Ru-Ru = 3.056(1) Angstroem; treatment of this dimer with CF3CO2H leads to formation of a mononuclear phosphinomethyldimethylsilanol complex H)(CO)2(CO2CF3)2*Et2O> in which Ru-OSi = 2.19 Angstroem, δ(OH) = 12.12, and the solvating Et2O molecule is H-bonded to the silanol-O with O ...O 2.64 Angstroem.

Full text of DOI:10.1039/c39830001523

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:hexacarbonylbis(μ-diphenylphosphinomethyldimethylsilyl)diruthenium(II)

Cas No:89087-15-0

R&D Labs maybe for 89087-15-0

Phantom-pharma

Contact:

Address:
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
SuZhou Hua-Emy Chemical Import and Export Co., LTD.

Contact:+86-512-88804994; +86-512-88804550;

Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China

Relevant to this article

Syntheses, structure, and optical properties of ladder-type fused azaborines

Doi:10.1021/ol060539n
(2006)
Synthesis and structure-activity relationships (SARs) of 1,5-diarylpyrazole cannabinoid type-1 (CB₁) receptor ligands for potential use in molecular imaging

Doi:10.1016/j.bmc.2006.01.047
(2006)
SYNTHESIS AND ANTIINFLAMMATORY ACTIVITY OF HYDROCHLORIDES OF SUBSTITUTED &α-AMINOACETOPHENONES

Doi:10.1007/BF00765023
(1983)
SYNTHESIS AND ANTIMICROBIAL ACTIVITY OF AMINO AND HYDROXY DERIVATIVES OF FURAN AND PYRROLIDINE

Doi:10.1007/BF00764688
(1983)
Benzimidazolone as potent chymase inhibitor: Modulation of reactive metabolite formation in the hydrophobic (P₁) region

Doi:10.1016/j.bmcl.2011.05.126
(2011)
Synthesis of Trisubstituted Vinyl Chlorides

Doi:10.1021/jo00164a036
(1983)

Article Doi