(η5-C5H5)Ru(PPh3)H3: A Stable Ruthenium(IV) Trihydride

DOI: 10.1039/c39830001278

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1278 - 1279 (1983)

Update date:2022-08-05

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Authors:

Davies, Stephen G.

Moon, Steven D.

Simpson, Stephen J.

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Article abstract of DOI:10.1039/c39830001278

Reduction of (η⁵-C5H5)Ru(PPh3)2Cl (2) with LiAlH4 in tetrahydrofuran leads to the trihydride (η⁵-C5H5)Ru(PPh3)H3 (1) together with, as a minor product, the expected monohydride (η⁵-C5H5)Ru(PPh3)2H (3) which can be prepared efficiently by treatment of the chloride (2) with NaOMe; reduction of (η⁵-C5H5)Ru(Ph2PCH2CH2PPh2)Cl (4) with LiAlH4 gives only the monohydride (η⁵-C5H5)Ru(Ph2PCH2CH2PPh2)H (5).

Full text of DOI:10.1039/c39830001278

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