(η5-C5H5)Ru(PPh3)H3: A Stable Ruthenium(IV) Trihydride

DOI: 10.1039/c39830001278

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1278 - 1279 (1983)

Update date:2022-08-05

Topics:

Authors:

Davies, Stephen G.

Moon, Steven D.

Simpson, Stephen J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830001278

Reduction of (η⁵-C5H5)Ru(PPh3)2Cl (2) with LiAlH4 in tetrahydrofuran leads to the trihydride (η⁵-C5H5)Ru(PPh3)H3 (1) together with, as a minor product, the expected monohydride (η⁵-C5H5)Ru(PPh3)2H (3) which can be prepared efficiently by treatment of the chloride (2) with NaOMe; reduction of (η⁵-C5H5)Ru(Ph2PCH2CH2PPh2)Cl (4) with LiAlH4 gives only the monohydride (η⁵-C5H5)Ru(Ph2PCH2CH2PPh2)H (5).

Full text of DOI:10.1039/c39830001278

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(η5-C5H5)Ru(PPh3)H3

Cas No:89252-27-7

R&D Labs maybe for 89252-27-7

LABTER PARMATECH(BEIJING)CO.,LTD

website:http://www.labter.com.cn/

Contact:+86-10-56330744

Address:NO.19,TIANRONG STREET,DAXING BIOMEDICIAL BASE ,ZHONGGUANCUN SCIENCE AND TECHNOLOGY PARK,BEIJING ,CHINA
Puyang Huicheng Electronic Material Co., Ltd

website:http://huichengchem.weba.testwebsite.cn/index_en.html

Contact:+86-393-8910800

Address:West Section Shengli Road, Puyang457000, China
Anyang Double Circle Auxiliary CO.,LTD

Contact:0086-134 6082 4403

Address:dongfeng road, anyang city, henan province,china
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA

Relevant to this article

SYNTHESIS OF ISOTHIOCYANATOPHOSPHORANES AND ISOTHIOCYANATOPHOSPHONIUM SALTS VIA OXIDATIVE ADDITION OF THIOCYANOGEN AND LIGAND SUBSTITUTION. NOVEL REAGENTS FOR CONVERTING HYDROXY GROUPS INTO THIOCYANATE AND ISOTHIOCYANATE FUNCTIONS UNDER MILD CONDITIONS

Doi:10.1016/S0040-4020(01)88637-3
(1983)
Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen XXXIII. Cycloaddition eines Silylens und eines Disilens an 2,2'-Bipyridyl

Doi:10.1016/0022-328X(88)87055-4
(1988)
Asymmetric synthesis of (S)-(-)-N-acetylcolchinol via Ullmann biaryl coupling

Doi:10.1016/j.tetlet.2007.04.103
(2007)
New quassinoid glucosides, picrasinoside-A, -B, -C, -D, -E, -F, and -G and new hemiacetals, picrasinol-A and -B, from the stem bark of Picrasma ailanthoides Planchon

Doi:10.1246/bcsj.58.1793
(1985)
Structure-activity relationship of new organic NLO materials based on push-pull azodyes. 1: Synthesis and molecular properties of the dyes

Doi:10.1002/prac.19983400204
(1998)
Synthesis and pharmacological characterization of nicotinic acetylcholine receptor properties of (+)- and (-)-pyrido-[3,4-b]homotropanes

Doi:10.1021/jm060122n
(2006)

Article Doi