Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 1295 - 1305 (1996)
Update date:2022-08-02
Topics:
Topaloglu, Isil
In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.
Contact:0086-0576-88551200,88886292 ,88880039
Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Hubei Onward Bio-Development Co., Ltd.
Contact:+86-718-8417012
Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Henan zhongda Biological Engineering Co., Ltd
Contact:86-28-18109029985
Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
Luzhou North Chemical Co., Ltd.
Contact:+86-830-2796784；+86-830-2796776
Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Contact:0086-22-2822 1962 / 2822 1963
Address:B-808, No. 1, North-South Street, Hexi District,
Doi:10.1016/S0022-328X(00)99119-8
(1984)Doi:10.1021/ja00323a004
(1984)Doi:10.1039/b517938f
(2006)Doi:10.1039/c39830001460
(1983)Doi:10.1007/s11176-005-0431-7
(2005)Doi:10.1021/ja060720r
(2006)
