Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 1295 - 1305 (1996)
Update date:2022-08-02
Topics:
Topaloglu, Isil
In this work, the reaction of the 16-electron species [Rh(η3-C8H13)-(η5-C 2B9H9Me2)] with PPh3 was investigated and the product, [exo-nido-Rh-(PPh3)2(η5-C2B 9H10Me2)], which is in an equilibrium with the closo analogue was characterized by 31p{1H}, 1H, 13C and 11B NMR spectroscopy. A mechanism for the complex formation is suggested which is related to the previously reported reactions between the 16-electron complex and PR3 (R = Me and Et) ligands.
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Doi:10.1016/S0022-328X(00)99119-8
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