Journal of the American Chemical Society p. 3089 - 3098 (1984)
Update date:2022-08-02
Topics:
Bergeron, Raymond J.
Kline, Steven J.
The solution structure of parabactin and its gallium(III) complex is evaluated with 300-MHz 1H NMR.The ligand is shown to exist in three separate conformers while the chelate appears to form the A cis chelate exclusively.Furthermore, the chelate is shown to exist in a 3:1 ratio of two diastereomeric forms that differ only in the disposition of the spermidine backbone.
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