Tetrahedron Letters p. 5691 - 5694 (1983)
Update date:2022-08-02
Topics:
Alper, Howard
Despeyroux, Bertrand
Woell, James B.
Terminal alkynes (including acetylene) undergo regioselective hydroesterification to unsaturated cis-diesters using PdCl2, CuCl2, HCl, alcohol, carbon monoxide, and oxygen; cis-monoesters are formed from internal alkynes.These reactions are complete within two hours at room temperature and atmospheric pressure.
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Doi:10.1021/ja052929v
(2005)Doi:10.1021/acs.orglett.6b00643
(2016)Doi:10.1021/jo060415o
(2006)Doi:10.1021/ja00324a030
(1984)Doi:10.1139/v91-231
(1991)Doi:10.1055/s-1984-30726
(1984)
