Tetrahedron Letters p. 5691 - 5694 (1983)
Update date:2022-08-02
Topics:
Alper, Howard
Despeyroux, Bertrand
Woell, James B.
Terminal alkynes (including acetylene) undergo regioselective hydroesterification to unsaturated cis-diesters using PdCl2, CuCl2, HCl, alcohol, carbon monoxide, and oxygen; cis-monoesters are formed from internal alkynes.These reactions are complete within two hours at room temperature and atmospheric pressure.
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(1984)
