LINEAR FREE-ENERGY RELATIONSHIPS BETWEEN STABILITY PARAMETERS OF SUBSTITUTED TROPYLIUM AND CYCLOPROPENYLIUM IONS AS MEASURED BY REDUCTION RATE WITH CHROMIUM(II), REDUCTION POTENTIAL, CHARGE-TRANSFER ENERGY, AND pKR+ VALUES

DOI: 10.1016/S0040-4020(01)90909-3

Source and publish data:

Tetrahedron p. 4011 - 4024 (1983)

Update date:2022-08-05

Topics:

Authors:

Okamoto, Kunio

Takeuchi, Ken'Ichi

Komatsu, Koichi

Kubota, Yasuhiro

Ohara, Riichiro

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)90909-3

Nine tropylium ions have been synthesized and the empirical stability parameters (i)-(iv) have been measured along with the parameters of known tropylium and cyclopropenylium ions: (i) the Cr(II)-ion reduction rate constant (k₂) in 10percent aq

Full text of DOI:10.1016/S0040-4020(01)90909-3

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