Chiral organolanthanides designed for asymmetric catalysis. Synthesis, characterization, and configurational interconversions of chiral, C1-symmetric organolanthanide halides, amides, and hydrocarbyls

Article abstract of DOI:10.1021/ja00101a047

This contribution describes the synthesis, structural systematics, absolute configurations, and structural interconversions of a series of C₁-symmetric lanthanide chloro, hydrocarbyl, and amide complexes/precatalysts based on chiral chelating M