PYRANOSIDIC HOMOLOGATION: PART II: EXTENDING THE CARBOHYDRATE TEMPLATE VIA VICINAL (SECONDARY) HYDROXYLS

DOI: 10.1016/S0040-4039(00)94211-4

Source and publish data:

Tetrahedron Letters p. 5823 - 5826 (1983)

Update date:2022-08-04

Topics:

Authors:

Magdzinski, Leon

Cweiber, Bruce

Fraser-Reid, Bert

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Article abstract of DOI:10.1016/S0040-4039(00)94211-4

The oxyrane ring of the dianhydro sugar (3b) is opened regioselectively by the dianion (4b), and reaction of the derived allylic alcohol (7b) with trifluoroacetic acid gives the oxa-cis-decalin (8b), which can be epoxidised selectively from the endo or ex

Full text of DOI:10.1016/S0040-4039(00)94211-4

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