A STABLE BINUCLEAR COMPLEX CONTAINING Pd-H-Pd BONDS

DOI: 10.1016/S0022-328X(00)98704-7

Source and publish data:

Journal of Organometallic Chemistry p. C52 - C54 (1984)

Update date:2022-07-30

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Authors:

Rimml, Heinrich

Venanzi, Luigi M.

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Article abstract of DOI:10.1016/S0022-328X(00)98704-7

The preparations of the binuclear hydrido-bridged cations <(terdentate ligand)Pd(μ-H)Pd(terdentate ligand)>⁺ from <(terdentate ligand)Pd(acetone)>⁺ and NaO2CH and <(terdentate ligand)Pd(μ-H)Pt(terdentate ligand)>⁺ from <(terdentate ligand)Pd(acetone)>⁺ and <(terdentate ligand)PtH> (terdentate ligand = 2,6-(Ph2PCH2)2C6H3) are reported.The preparation of the cation <(terdentate ligand)Pt(μ-H)Pt(terdentate ligand)>⁺ is also reported.

Full text of DOI:10.1016/S0022-328X(00)98704-7

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