Phosphine-catalyzed addition/cycloaddition domino reactions of β′-Acetoxy allenoate: Highly stereoselective access to 2-oxabicyclo[3.3.1]nonane and Cyclopenta[a]pyrrolizine

DOI: 10.1021/jacs.5b03273

Source and publish data:

Journal of the American Chemical Society p. 6400 - 6406 (2015)

Update date:2022-07-30

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Authors:

Gu, Yiting

Hu, Pengfei

Ni, Chunjie

Tong, Xiaofeng

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Article abstract of DOI:10.1021/jacs.5b03273

Two classes of phosphine-catalyzed addition/cycloaddition domino reactions of β′-acetoxy allenoate 1 have been developed. The reaction of 1 with 2-acyl-3-methyl-acrylonitrile 2 readily occurs to give 2-oxabicyclo[3.3.1]nonane 3, furnishing the β′-addition

Full text of DOI:10.1021/jacs.5b03273

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