A Thermally Induced Novel Fragmentation Reaction of Transition Metal Silylcarbene Complexes

DOI: 10.1039/c39840000013

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 13 - 14 (1984)

Update date:2022-08-04

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Authors:

Schubert, Ulrich

Hoernig, Hannelore

Erdmann, Kai-Uwe

Weiss, Karin

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Article abstract of DOI:10.1039/c39840000013

The carbene complexes (CO)5WC(OEt)SiPh3 (1) and (CO)5WC(NEt2)SiPh3 (2) thermally decompose to give triphenylsilane, ethylene, and W(CO)6 or (CO)5WCNEt, respectively, while in the presence of moist CO, 2O is formed, believed to arise via the ketene intermediate, Ph3Si(EtO)C=C=O.

Full text of DOI:10.1039/c39840000013

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