Journal of Organic Chemistry p. 2074 - 2076 (1984)
Update date:2022-08-04
Topics:
Gassman, Paul G.
Carroll, Glenn T.
A radical chain process has been established for the addition of a series of ketones across the C1-C3 bond of bicyclo<1.1.0>butane and its methylated derivatives.For certain ketones, capture of an acyl radical intermediate, generated in a Norrish type I cleaveage of the ketone, competes effectively with the radical chain process.
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