Silylmethyl Radical Cyclization: New Stereoselective Method for 1,3-Diol Synthesis from Allylic Alcohols

DOI: 10.1021/jo00186a049

Source and publish data:

Journal of Organic Chemistry p. 2298 - 2300 (1984)

Update date:2022-08-03

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Authors:

Nishiyama, Hisao

Kitajima, Toshio

Matsumoto, Makoto

Itoh, Kenji

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Article abstract of DOI:10.1021/jo00186a049

Cyclizations of (bromomethyl)dimethylsilyl allylic ethers by treatment with tri-n-butyltin hydride in a free-radical process followed by oxidation in a one-pot manner with hydrogen peroxide gave th corresponding 1,3-diols predominantly with high stereoselectivity.

Full text of DOI:10.1021/jo00186a049

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