Tetrahedron Letters p. 2595 - 2598 (1990)
Update date:2022-08-04
Topics: Syntheses Stereoselective Preparation Regioselective
Ducoux, Jean-Philippe
Menez, Patrick Le
Kunesch, Nicole
Kunesch, Gerhard
Wenkert, Ernest
Two pheromones, (Z)-6,(Z)-11-hexadecadien-1-yl acetate (from Eudia pavonia) and gossyplure, have been synthesized each by two consecutive sequences of nickel-assisted Grignard reactions with cyclic enol ethers and the preparation of Grignard reagents from the resultant alcohols, followed each by copper-promoted Grignard reaction with a small-ring ether and subsequent acetylation.
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