Journal of Organometallic Chemistry p. 201 - 214 (1984)
Update date:2022-09-26
Topics:
Postnov, V. N.
Andrianov, V. G.
Struchkov, Yu. T.
Baran, A. M.
Sazonova, V. A.
The asymmetric induction in the synthesis of pyrazolines with ferrocenyl and phenylbutadienyliron tricarbonyl substituents is estimated.Diastereomeric selectivity is shown to be sufficiently high both by the induction of a chiral centre by a chirality plane and vice versa.The molecular geometry of diastereomeric 1-acetyl-3-<4-phenylbutadienyliron tricarbonyl>-5-ferrocenylpyrazolines is discussed.
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