Journal of Organometallic Chemistry p. 215 - 222 (1984)
Update date:2022-08-02
Topics:
Baird, Gordon J.
Davies, Stephen G.
The cyano complexes (η5-C5H5)M(Ph2PCH2CH2PPh2)CN (4, M = Fe; 6, M = Ru) and (η5-C5H5)Ru(PPh3)2CN (5) have been prepared by treatment of the corresponding chlorides with methanolic potassium cyanide.The nucleophilicity of the cyano ligand has been demonstrated by the reactions of 5 with a variety of mild electrophiles (MeI, EtI, allyl bromide, PhCH2Br, ICH2CH2OH and cyclohexene oxide) to form the corresponding isonitrile cations.
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Doi:10.1246/cl.1984.441
(1984)Doi:10.1021/jo060566r
(2006)Doi:10.1021/jo00870a024
(1976)Doi:10.1002/anie.200600642
(2006)Doi:10.1246/bcsj.57.142
(1984)Doi:10.1134/S1070428012070044
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