SYNTHESIS AND CHIROPTICAL PROPERTIES OF SOME TERTIARY AMINES CONTAINING A PYRIDINE RING

Article abstract of DOI:10.1007/BF00505856

Tertiary amines of the pyridine series containing an α-phenylethylamine residue have been synthesized.The IR spectra and circular dichroisms of these amines have been measured in the 400 - 200 nm interval, and an assignment of the bands has been made.It is suggested that the long-wave absorption band in the 315 nm region for N-methyl-N-<2-(pyridin-2-yl)ethyl>-α-phenylethylamine and the Cotton effect corresponding to it are due to an intramolecular CTC.