Journal of the Chemical Society. Chemical communications p. 134 - 135 (1984)
Update date:2022-07-30
Topics:
Clawson, Paul
Lunn, Patricia M.
Whiting, Donald A.
2,3-Bis(p-methoxyphenyl)oxirane (6) rearranges, with C-O cleavage, to the carbonyl compounds (8) and (9) on irradiation, direct or triplet sensitised, and thermally; in contrast C-C cleavage is observed with dicyanoanthracene as electron-transfer sensitiser, and the resulting intermediate can be trapped by dipolarophiles in synthetically useful reactions.
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