Chiral phosphinyl analogues of 2-C-arylmorpholinols: 2-aryl-3,5-diphenyl-[1,4,2]-oxazaphosphinanes

DOI: 10.1016/j.tetasy.2006.05.003

Source and publish data:

Tetrahedron Asymmetry p. 1402 - 1408 (2006)

Update date:2022-07-29

Topics:

Authors:

Volle, Jean-Noel

Virieux, David

Starck, Matthieu

Monbrun, Jerome

Clarion, Ludovic

Pirat, Jean-Luc

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Article abstract of DOI:10.1016/j.tetasy.2006.05.003

(2R,3R,5R)-2-Aryl-3,5-diphenyl-[1,4,2]-oxazaphosphinanes 6, analogues of C-arylmorpholinol 3, were prepared with diastereomeric excess higher than 94%, via a three step sequence: (i) diastereoselective addition-cyclization reaction from methyl hypophosphi

Full text of DOI:10.1016/j.tetasy.2006.05.003

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Product name:(2S,3R,5R)-(-)-3,5-diphenyl-2-oxo-[1,4,2]-oxazaphosphinane

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