STUDIES ON NUCLEOPHILIC ADDITIONS AT BRIDGING VINYL LIGANDS IN TRIOSMIUM CLUSTERS

DOI: 10.1016/0022-328X(84)80055-8

Source and publish data:

Journal of Organometallic Chemistry p. 87 - 94 (1984)

Update date:2022-08-04

Topics:

Authors:

Deeming, Antony J.

Manning, Peter J.

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Article abstract of DOI:10.1016/0022-328X(84)80055-8

The bridging vinyl clusters (R = H, Ph, or n-Bu) react with PMe2Ph to give the zwitterionic adducts which contain μ₂-alkylidene ligands.The adducts are not formed so readily when R = Ph or n-Bu but

Full text of DOI:10.1016/0022-328X(84)80055-8

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