UEBER STERISCH GEHINDERTE FREIE RADIKALE XI. DIE ERSTE REVERSIBLE THERMISCHE DISSOZIATION VON DISILANEN R3Si-SiR3 ZU SILYLRADIKALEN R3Si. UND VON DIGERMANEN R3Ge-GeR3 ZU GERMYLRADIKALEN R3Ge.

DOI: 10.1016/0022-328X(84)85144-X

Source and publish data:

Journal of Organometallic Chemistry p. 179 - 192 (1984)

Update date:2022-07-29

Topics:

Authors:

Neumann, Wilhelm P.

Schultz, Klaus-Dieter

Vieler, Robert

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Article abstract of DOI:10.1016/0022-328X(84)85144-X

The Si-Si bond in hexamesityldisilane dissociates reversibly even between -60 and -32 deg C (ΔH_diss 19.0 +/- 2 kcal mol^-1) and the Ge-Ge bond in hexamesityldigermane reversibly between -12 and +53 deg C (ΔH_diss 20.7 +/- 2

Full text of DOI:10.1016/0022-328X(84)85144-X

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