UEBER STERISCH GEHINDERTE FREIE RADIKALE XI. DIE ERSTE REVERSIBLE THERMISCHE DISSOZIATION VON DISILANEN R3Si-SiR3 ZU SILYLRADIKALEN R3Si. UND VON DIGERMANEN R3Ge-GeR3 ZU GERMYLRADIKALEN R3Ge.

DOI: 10.1016/0022-328X(84)85144-X

Source and publish data:

Journal of Organometallic Chemistry p. 179 - 192 (1984)

Update date:2022-07-29

Topics:

Authors:

Neumann, Wilhelm P.

Schultz, Klaus-Dieter

Vieler, Robert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(84)85144-X

The Si-Si bond in hexamesityldisilane dissociates reversibly even between -60 and -32 deg C (ΔH_diss 19.0 +/- 2 kcal mol^-1) and the Ge-Ge bond in hexamesityldigermane reversibly between -12 and +53 deg C (ΔH_diss 20.7 +/- 2

Full text of DOI:10.1016/0022-328X(84)85144-X

Products guided by the article

Product name:Digermane, hexakis(pentamethylphenyl)-

Cas No:90753-02-9

R&D Labs maybe for 90753-02-9

BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
Jinan Jianfeng Chemical Co., Ltd

Contact:0086-531-88110457

Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:--

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China

Relevant to this article

Synthesis of isotopically labeled all-trans retinals for DNP-enhanced solid-state NMR studies of retinylidene proteins

Doi:10.1002/jlcr.3576
(2018)
Cryovoltammetrically probing functional group reductive cleavage: Alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable

Doi:10.1039/b606638k
(2006)
Molecular tongs containing amino acid mimetic fragments: New inhibitors of wild-type and mutated HIV-1 protease dimerization

Doi:10.1021/jm060576k
(2006)
Discovery and SAR of cinnolines/quinolines as liver X receptor (LXR) agonists with binding selectivity for LXRβ

Doi:10.1016/j.bmc.2009.04.012
(2009)
4-(DIMETHYLAMINO)BENZYLIDENE-AMINO.

Doi:10.1246/bcsj.57.1411
(1984)
Synthesis of homoallylic amines via the palladium-catalyzed decarboxylative coupling of amino acid derivatives

Doi:10.1021/ja063115x
(2006)

Article Doi