Tetrahedron Letters p. 5253 - 5256 (1981)
Update date:2022-07-30
Gassman, Paul G.
Talley, John J.
H/α-CN rate ratios have been derived for the solvolysis of sulfonate esters of endo-tricyclo<3.2.1.02,4>octan anti-8-ol and tricyclo<2.2.1.02,6>heptan-3-ol.The role of the α-cyano moiety in the stabilization of highly delocalized cations has been evaluated.
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