Direct conversion of tert-butyl 2-hydroxyalkyl sulfides to 1,3-oxathiolanes

DOI: 10.1016/j.tet.2005.10.026

Source and publish data:

Tetrahedron p. 931 - 936 (2006)

Update date:2022-08-04

Topics:

Authors:

Porter, Michael J.

Saez, Fabienne

Sandhu, Amandeep Kaur

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Article abstract of DOI:10.1016/j.tet.2005.10.026

tert-Butyl 2-hydroxyalkyl sulfides, prepared by reaction of epoxides with 2-methylpropane-2-thiol, are converted directly to 1,3-oxathiolanes upon treatment with pivalaldehyde and boron trifluoride diethyl etherate in the presence of thioanisole.

Full text of DOI:10.1016/j.tet.2005.10.026

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