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A tantalum(V) carbene complex: Formation of a carbene-bis(phenoxide) ligand by sequential proton and hydride abstraction

DOI: 10.1021/ic0608492

Source and publish data:

Inorganic Chemistry p. 6580 - 6582 (2006)

Update date:2022-09-26

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Authors:

Watanabe, TakahitoWatanabe, Takahito

Matsuo, TsukasaMatsuo, Tsukasa

Kawaguchi, HiroyukiKawaguchi, Hiroyuki

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Article abstract of DOI:10.1021/ic0608492

Proton and subsequent hydride abstraction from the bis(phenoxide) ligand of the trimethyltantalum(V) complex affords a cationic tantalum(V) carbene complex, in which two phenoxide groups are linked to the carbene center. The electrophilic nature of the carbene functionality is demonstrated by the reaction with PPh3.

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Full text of DOI:10.1021/ic0608492

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