A VINYLSILANE ROUTE TO TRANS-7a-METHYLHYDRIND-4-EN-1,6-DIONE

DOI: 10.1016/S0040-4039(01)80120-9

Source and publish data:

Tetrahedron Letters p. 1231 - 1234 (1984)

Update date:2022-07-30

Topics:

Authors:

Denmark, Scott E.

Germanas, Juris P.

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Article abstract of DOI:10.1016/S0040-4039(01)80120-9

A stereoselective synthesis of the title compound is described.The overall yield is 34percent starting with 2-methyl-2-cyclopentenone.The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence.

Full text of DOI:10.1016/S0040-4039(01)80120-9

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