Stereoselective synthesis of functionalized 1,3 diols through the tandem isomerization-aldolization reaction mediated by nickel catalysts

DOI: 10.1016/j.tetlet.2006.08.125

Source and publish data:

Tetrahedron Letters p. 7745 - 7748 (2006)

Update date:2022-08-02

Topics:

Authors:

Petrignet, Julien

Roisnel, Thierry

Grée, René

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Article abstract of DOI:10.1016/j.tetlet.2006.08.125

A new approach to functionalized 1,3 diols, such as 15, is described using as the key step the tandem isomerization-aldolization reaction of allylic alcohols 1. The chiral imidazolidine group is shown to play a key role for the stereocontrol during aldoli

Full text of DOI:10.1016/j.tetlet.2006.08.125

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