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S. D. Stamatov, J. Stawinski
LETTER
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(iii) the method seems to be general and introduces 2-O-
acylated haloglycerols 7–10 as versatile three-carbon
units useful in the preparation of bis(acylated) vicinal ha-
lohydrins or asymmetric triglyceride precursors; (iv) the
method makes use of commercially available reactants
and preparations can easily be scaled up.
Acknowledgment
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Appl. Chem. 1986, 58, 395. (b) Martin, J. D.; Perez, C.;
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Financial support from the Swedish Natural Science Research
Council and the Swedish Foundation for Strategic Research is gra-
tefully acknowledged.
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343.
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TFAA and tetrabutylammonium halides or with TFAA and
TMSBr in the presence of pyridine, occurred without acyl
migration and involved a nucleophilic opening of the
oxirane ring with halide ion, facilitated by electrophilic
catalysis exerted by TFAA.
Synlett 2006, No. 14, 2251–2255 © Thieme Stuttgart · New York