Trialkylsilyl(hydrido)(ethylene)pentamethylcyclopentadienylrhodium(III) Complexes

DOI: 10.1039/c39850001374

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1374 - 1375 (1985)

Update date:2022-08-03

Topics:

Authors:

Bentz, Peter O.

Ruiz, Jose

Mann, Brian E.

Spencer, Catriona M.

Maitlis, Peter M.

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Article abstract of DOI:10.1039/c39850001374

The equilibria <(C5Me5)Rh(H)2(SiEt3)2> + C2H4 -->/<-- HSiEt3 + <(C5Me5)Rh(H)(SiEt3)(C2H4)>, and <(C5Me5)Rh(H)(SiEt3)(C2H4)> + C2H4 -->/<-- HSiEt3 + <(C5Me5)Rh(C2H4)2>, can be induced either thermally or photochemically starting from either side.

Full text of DOI:10.1039/c39850001374

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